Polar Vector Property of the Stationary State of Condensed Molecular Matter

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Polar Vector Property of the Stationary State of Condensed Molecular Matter

Crystalline phases undergoing 180 ◦ orientational disorder of dipolar entities in the seed or at growing (hkl) faces will show a polar vector property described by ∞/mm symmetry. Seeds and crystals develop a bi-polar state (∞/mm), where domains related by a mirror plane m allow for a ∞m symmetry in each domain. The polarity of domains is due to energetic favorable interactions at the object-to-...

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Symmetry and the polar state of condensed molecular matter

Polar molecular crystals seem to contradict a quantum mechanical statement, according to which no stationary state of a system features a permanent electrical polarization. By stationary we understand here an ensemble for which thermal averaging applies. In the language of statistical mechanics we have thus to ask for the thermal expectation value of the polarization in molecular crystals. Nucl...

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ژورنال

عنوان ژورنال: Symmetry

سال: 2014

ISSN: 2073-8994

DOI: 10.3390/sym6040844